S,O-ligand-promoted palladium-catalyzed C-H olefination of arenes with allylic substrates

Naksomboon, K, Álvarez-Casao, Y, Uiterweerd, M, Westerveld, N, Maciá, B and Fernández-Ibáñez, MÁ (2018) S,O-ligand-promoted palladium-catalyzed C-H olefination of arenes with allylic substrates. Tetrahedron Letters, 59 (4). pp. 379-382. ISSN 0040-4039

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Official URL: https://doi.org/10.1016/j.tetlet.2017.12.047

Abstract

An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone.

Item Type:	Article (Article)
Peer-reviewed:	Yes
Date Deposited:	16 Jan 2018 09:01
Publisher:	Elsevier
Additional Information:	This is an Open Access article published in Tetrahedron Letters, published by Elsevier, copyright The Author(s).
Divisions:	Faculties > Science and Engineering
Subject terms:	0305 Organic Chemistry, Organic Chemistry
URI:	https://e-space.mmu.ac.uk/id/eprint/619739
DOI:	https://doi.org/10.1016/j.tetlet.2017.12.047
ISSN	0040-4039

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