Low-concentration detection of H2S using temperature-dependent Cr-doped cobalt-oxide gas sensors

Manikandan, V, Ayyannan, G, Mane, Rajaram S, Petrila, Iulian, Selvaraj, Manickam, Crapnell, Robert D ORCID: https://orcid.org/0000-0002-8701-3933 and Banks, Craig E ORCID: https://orcid.org/0000-0002-0756-9764 (2024) Low-concentration detection of H2S using temperature-dependent Cr-doped cobalt-oxide gas sensors. Journal of Environmental Chemical Engineering, 12 (3). 112697. ISSN 2213-3437

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Abstract

Among the existing metal-oxide gas sensors, cobalt oxide has the flexibility to revise the morphology through Cr-dopant to enhance sensing properties. Sensitive-surface of the chromium-doped cobalt oxide has proven its effective sensing nature to hydrogen sulfide gas. Interestingly, chromium-dopant increases the surface area, leading to particle size reduce and produces the more active sites for gas molecules. Also, the dopant creates impurity phases on the material which extends the sites for more reaction. To confirms these characteristics, the photoluminescence spectra showed intense peak that mimics the faster transport of electron to accelerate the sensing reaction. According to sensing measurement, the doped sensor is showing three-fold increase of response to 10 ppm gas and also, it detects the 2 ppm efficiently. The doped sensor warrants the stable response to gas due to higher reproducibility. Notably, the doped sensor detects the 1 ppm of gas at 120 s and recovery itself around 200 s. The doped sensor imparts response at room-temperature, affirming sensitive-surface. The doped sensor has shown the capable under humidity environment through response.