Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization

Leonard, Elisabeth LR, Akien, Geoffrey R, Britten, Thomas K, Kazi, Nahin, Roberts, Dean D and McLaughlin, Mark G (2023) Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis and Catalysis, 365 (22). pp. 3872-3875. ISSN 1615-4150

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Official URL: http://dx.doi.org/10.1002/adsc.202300917

Abstract

We present a rapid (0.25–1 h), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22–98%) and, in most cases, as a single geometric isomer. Furthermore, a possible allylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.

Item Type:	Article (Rapid Communication)
Peer-reviewed:	Yes
Date Deposited:	16 Nov 2023 08:34
Publisher:	Wiley
Additional Information:	This is the peer reviewed version of the following communication: E. L. R. Leonard, G. R. Akien, T. K. Britten, N. Kazi, D. D. Roberts, M. G. McLaughlin, Adv. Synth. Catal. 2023, 365, 3872., which has been published in final form at https://doi.org/10.1002/adsc.202300917. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
Divisions:	Faculties > Science and Engineering
Subject terms:	0302 Inorganic Chemistry, 0305 Organic Chemistry, 0904 Chemical Engineering, Organic Chemistry
URI:	https://e-space.mmu.ac.uk/id/eprint/633145
DOI:	https://doi.org/10.1002/adsc.202300917
ISSN	1615-4150
e-ISSN	1615-4169