Brønsted Acid Catalyzed Peterson Olefinations

Britten, Thomas Kenton and McLaughlin, Mark Gerard ORCID: https://orcid.org/0000-0002-5999-4703 (2020) Brønsted Acid Catalyzed Peterson Olefinations. The Journal of Organic Chemistry, 85 (2). pp. 301-305. ISSN 0022-3263

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Official URL: https://pubs.acs.org/doi/10.1021/acs.joc.9b02489

Abstract

A mild and facile Peterson olefination has been developed employing low catalyst loading of the Brønsted acid HNTf2. The reactions are typically performed at room temperature, with the reaction tolerant to a range of useful functionalities. Furthermore, we have extended this methodology to the synthesis of enynes.

Item Type:	Article
Peer-reviewed:	Yes
Date Deposited:	02 Dec 2019 11:33
Publisher:	American Chemical Society (ACS)
Additional Information:	This is an Author Accepted Manuscript of a forthcoming paper accepted for publication by American Chemical Society in Journal of Organic Chemistry
Divisions:	Faculties > Science and Engineering
Subject terms:	0304 Medicinal and Biomolecular Chemistry, 0305 Organic Chemistry, 0302 Inorganic Chemistry, Organic Chemistry
Report number:	acs.joc.9b02489
URI:	https://e-space.mmu.ac.uk/id/eprint/624491
DOI:	https://doi.org/10.1021/acs.joc.9b02489
ISSN	0022-3263
e-ISSN	1520-6904

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