Formation of Quaternary Stereocentres by Copper-Catalysed Enantioselective Conjugate Addition Reaction

Maciá Ruiz, B (2015) Formation of Quaternary Stereocentres by Copper-Catalysed Enantioselective Conjugate Addition Reaction. In: Progress in Enantioselective Cu(I)-catalyzed Formation of Stereogenic Centers. Topics in Organometallic Chemistry, 58 . Springer Verlag, pp. 41-98. ISBN 9783319334127 (hardcover); 9783319815053 (softcover); 9783319334141 (online)

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Official URL: https://doi.org/10.1007/3418_2015_158

Abstract

Remarkable progress in copper-catalysed enantioselective conjugate addition (ECA) reactions has been made over the past decade. This enantioselective transformation now allows the challenging formation of chiral quaternary centres by addition of different nucleophiles to trisubstituted á,â-unsaturated systems. This chapter summarises the developments in the area.

Item Type:	Book Section
Peer-reviewed:	Yes
Gold OA (Books and Book Chapters):	No
Date Deposited:	20 Apr 2017 10:08
Publisher:	Springer Verlag
Additional Information:	This is an Author Accepted Manuscript of a paper accepted for publication in Progress in Enantioselective Cu(I)-catalyzed Formation of Stereogenic Centers, published by and copyright Springer International Publishing Switzerland.
Divisions:	Organisation > Science and Engineering
Subject terms:	Conjugate addition, Copper catalysis, Enantioselective catalysis, Quaternary centres, Science & Technology, Physical Sciences, Chemistry, Inorganic & Nuclear, Chemistry, Organic, Chemistry, Conjugate addition, Copper catalysis, Enantioselective catalysis, Quaternary centres, SUBSTITUTED CYCLIC ENONES, TERTIARY ORGANOBORONIC ESTERS, CARBON STEREOGENIC CENTERS, ARYL ALUMINUM REAGENTS, N-HETEROCYCLIC CARBENE, GRIGNARD-REAGENTS, TRISUBSTITUTED ENONES, ASYMMETRIC-SYNTHESIS, ORGANOMETALLIC REAGENTS, DIALKYLZINC REAGENTS, 0302 Inorganic Chemistry, 0305 Organic Chemistry, 0399 Other Chemical Sciences, Organic Chemistry
URI:	https://e-space.mmu.ac.uk/id/eprint/396
DOI:	https://doi.org/10.1007/3418_2015_158
ISSN	1436-6002
e-ISSN	1616-8534

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