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    Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization

    Leonard, Elisabeth LR, Akien, Geoffrey R, Britten, Thomas K, Kazi, Nahin, Roberts, Dean D and McLaughlin, Mark G (2023) Synthesis of Diverse Allylsilanes Employing Brønsted Acid Catalyzed Reductive Functionalization. Advanced Synthesis and Catalysis, 365 (22). pp. 3872-3875. ISSN 1615-4150

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    Abstract

    We present a rapid (0.25–1 h), method to produce functionalised allylsilanes from readily available vinylsilanes. Employing a Brønsted acid catalysed dehydration as the key step, allylsilanes are produced in good yields (22–98%) and, in most cases, as a single geometric isomer. Furthermore, a possible allylation‐Cope pathway was discovered for certain substrates and attempts to optimise this are described.

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