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Brønsted Acid Catalyzed Peterson Olefinations

Britten, Thomas Kenton and McLaughlin, Mark Gerard (2019) Brønsted Acid Catalyzed Peterson Olefinations. The Journal of Organic Chemistry. ISSN 0022-3263

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Abstract

A mild and facile Peterson olefination has been developed employing low catalyst loading of the Brønsted acid HNTf2. The reactions are typically performed at room temperature, with the reaction tolerant to a range of useful functionalities. Furthermore, we have extended this methodology to the synthesis of enynes.

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