e-space
Manchester Metropolitan University's Research Repository

    Flow micro-calorimetry and diffuse reflectance Fourier transform infrared spectroscopy studies in filled polyurethane adhesives by using dimethyl adipate as a model compound

    Donate-Robles, J, Liauw, Christopher and Martín-Martínez, JM (2014) Flow micro-calorimetry and diffuse reflectance Fourier transform infrared spectroscopy studies in filled polyurethane adhesives by using dimethyl adipate as a model compound. International Journal of Adhesion and Adhesives, 48. pp. 43-50. ISSN 0143-7496

    [img]
    Preview
    Accepted Version
    Available under License In Copyright.

    Download (1MB) | Preview

    Abstract

    Interactions between nano-scale filler particles (precipitated calcium carbonate, carbon black and fumed silica) and model compounds (dimethyl adipate and butan-2-one) are quantified using flow micro-calorimetry (FMC) and diffuse reflectance Fourier transform infrared spectroscopy (DRFTIRS). Carbonyl groups of dimethyl adipate interact strongly with silanol groups on the fumed silica surface but weakly with the uncoated precipitated calcium carbonate. In general, higher surface area loading imparts high level of adsorption because of the nanofiller has more adsorption sites. Carbon black is an exception likely due to the less accessible surface groups and the presence of relatively important amount of micropores. © 2013 Elsevier Ltd.

    Impact and Reach

    Statistics

    Activity Overview
    6 month trend
    500Downloads
    6 month trend
    275Hits

    Additional statistics for this dataset are available via IRStats2.

    Altmetric

    Repository staff only

    Edit record Edit record