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S,O-ligand-promoted palladium-catalyzed C-H olefination of arenes with allylic substrates

Naksomboon, K and Álvarez-Casao, Y and Uiterweerd, M and Westerveld, N and Maciá, B and Fernández-Ibáñez, MÁ (2017) S,O-ligand-promoted palladium-catalyzed C-H olefination of arenes with allylic substrates. Tetrahedron Letters, 59 (4). pp. 379-382. ISSN 0040-4039

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Abstract

An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone.

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