Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Lewis-Alleyne, Lesley C., Murphy-Jolly, Makeba B., Le Goff, Xavier F. and Caffyn, Andrew J. M. (2010) Synthesis and complexation of heptafluoroisopropyldiphenylphosphine. Dalton transactions, 39 (5). pp. 1198-1200. ISSN 1477-9234

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Abstract

We report a one-step synthesis of the phosphine, PPh2iC3F7 from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)5PPh2iC3F7 was synthesised and the synthesis and structure of trans-PtCl2(PPh2iC3F7)2 are described. PPh2iC3F7 was found to be a bulky electron-withdrawing ligand.

Item Type:	Article
Peer-reviewed:	No
Date Deposited:	11 Mar 2010 12:17
Publisher:	Royal Society of Chemistry
Additional Information:	Full-text of this article is not available in this e-prints service. This article was originally published following peer-review in Dalton Transactions, published by and copyright Royal Society of Chemistry.
Divisions:	Faculties > Science and Engineering
URI:	https://e-space.mmu.ac.uk/id/eprint/94103
DOI:	https://doi.org/10.1039/b918348e
ISSN	1477-9234

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