Dehydrogenation of a tertiary amine-borane by a rhenium complex

Sohail, M ORCID: https://orcid.org/0000-0002-8221-818X, Moncho, S, Brothers, EN and Bengali, AA (2014) Dehydrogenation of a tertiary amine-borane by a rhenium complex. Chemical Communications, 50 (44). pp. 5874-5877. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/c4cc01771d

Abstract

Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

Item Type:	Article (Article)
Peer-reviewed:	Yes
Date Deposited:	05 Sep 2024 15:27
Publisher:	Royal Society of Chemistry (RSC)
Additional Information:	For copyright reasons, full-text access is not available through this repository
Divisions:	Faculties > Science and Engineering Faculties > Science and Engineering > Department of Natural Sciences
Subject terms:	03 Chemical Sciences, Organic Chemistry, 34 Chemical sciences, 40 Engineering
URI:	https://e-space.mmu.ac.uk/id/eprint/635424
DOI:	https://doi.org/10.1039/c4cc01771d
ISSN	1359-7345
e-ISSN	1364-548X

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