Sohail, M ORCID: https://orcid.org/0000-0002-8221-818X, Moncho, S, Brothers, EN and Bengali, AA
(2014)
Dehydrogenation of a tertiary amine-borane by a rhenium complex.
Chemical Communications, 50 (44).
pp. 5874-5877.
ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/c4cc01771d
Abstract
Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.
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