Efficient Photodegradation of Thiocyanate Ions in Mining Wastewater Using a ZnO-BiOI Heterojunction

Ashiegbu, Darlington C ORCID: https://orcid.org/0000-0003-2204-6248, Nkhoesa, David, Erasmus, Rudolph and Potgieter, Herman Johanes ORCID: https://orcid.org/0000-0003-2833-7986 (2024) Efficient Photodegradation of Thiocyanate Ions in Mining Wastewater Using a ZnO-BiOI Heterojunction. Materials, 17 (15). 3832.

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Abstract

Mining industries have long relied on cyanidation as the primary method for gold extraction, but this process generates thiocyanates as a problematic byproduct, posing challenges for wastewater treatment and recycling. The stability of thiocyanates makes their reduction or elimination in mining wastewater difficult. In this study, a p-n heterojunction of ZnO and BiOI was created and evaluated for its ability to photodegrade thiocyanate ions under simulated solar conditions. Various analytical techniques revealed a highly porous structure with a sponge-like morphology and agglomeration in the synthesized heterojunction. The compound exhibited crystalline patterns without impurity peaks, a slight red shift in absorbance, and Type IV isotherm adsorption. The synthesized heterostructure achieved the complete destruction of thiocyanate ions in less than 30 min. The investigation of different process parameters indicated that the destruction of the contaminant by the heterostructure was influenced by the initial thiocyanate concentration, which decreased as the thiocyanate concentration increased. The peak photodestruction reaction was observed at pH 7. By applying a pseudo-first-order kinetic model, it was found that increasing the catalyst mass to 15 mg raised the rate constant from 0.188 to 0.420 min−1, while increasing the pH to 10 led to a 3.5-fold reduction. The strong correlation between the observed data and the predicted values of the pseudo-first-order kinetic model was indicated by the observed (R2) values. The findings of this study hold potential significance for mining industries, as it offers a potential solution for eliminating cyanide and thiocyanates from mining wastewater. The elimination of thiocyanate generation in the cyanidation process is crucial for mining companies, making this study valuable for the industry.