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Aza-Peterson Olefinations: Rapid Synthesis of (E)-Alkenes

Britten, Thomas K and Basson, Ashley James and Roberts, Dean David and McLaughlin, Mark Gerard (2021) Aza-Peterson Olefinations: Rapid Synthesis of (E)-Alkenes. Synthesis. ISSN 0039-7881

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Abstract

An aza-Peterson olefination methodology to access 1,3-dienes and stilbene derivatives from the corresponding allyl- or benzyl trimethylsilanes is described. Silanes can be deprotonated using Schlosser’s base and added into N-phenyl imines or ketones to directly give the desired products in high yields.

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