Aza-Peterson Olefinations: Rapid Synthesis of (E)-Alkenes

Britten, Thomas K, Basson, Ashley James, Roberts, Dean David and McLaughlin, Mark Gerard (2021) Aza-Peterson Olefinations: Rapid Synthesis of (E)-Alkenes. Synthesis, 53 (19). pp. 3535-3544. ISSN 0039-7881

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Abstract

An aza-Peterson olefination methodology to access 1,3-dienes and stilbene derivatives from the corresponding allyl- or benzyl trimethylsilanes is described. Silanes can be deprotonated using Schlosser’s base and added into N-phenyl imines or ketones to directly give the desired products in high yields.

Item Type:	Article
Peer-reviewed:	Yes
Date Deposited:	06 May 2021 11:37
Publisher:	Georg Thieme Verlag KG
Additional Information:	© 2021 Thieme.
Divisions:	Faculties > Science and Engineering
Subject terms:	Organic Chemistry, 0301 Analytical Chemistry, 0305 Organic Chemistry
URI:	https://e-space.mmu.ac.uk/id/eprint/627594
DOI:	https://doi.org/10.1055/a-1493-6670
ISSN	0039-7881
e-ISSN	1437-210X

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