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    Sustainable Access to 5‐Amino‐Oxazoles and Thiazoles via Calcium Catalyzed Elimination‐Cyclization with Isocyanides

    Basson, Ashley James and McLaughlin, Mark Gerard (2021) Sustainable Access to 5‐Amino‐Oxazoles and Thiazoles via Calcium Catalyzed Elimination‐Cyclization with Isocyanides. ChemSusChem: chemistry and sustainability, energy and materials, 14 (7). pp. 1696-1699. ISSN 1864-5631

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    Abstract

    Herein we report a sustainable, modular, rapid and high yielding transformation to afford densely functionalized 5‐aminooxazoles and thiazoles. The reaction is tolerant to a wide range of functional groups, and is typically complete in under 30 minutes. Furthermore, the described transformation is inherently green in relation to the catalyst and solvent choice as well as producing environmentally benign alcoholic by‐products.

    Item Type: Article
    Peer-reviewed: Yes
    Date Deposited: 01 Mar 2021 14:43
    Publisher: Wiley
    Additional Information: This is an Open Access article which appeared in ChemSusChem, published by Wiley.
    Divisions: Faculties > Science and Engineering
    Subject terms: Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Green & Sustainable Science & Technology, Chemistry, Science & Technology - Other Topics, calcium catalysis, cyclisation, isocyanides, oxazoles, thiazoles, calcium catalysis, cyclisation, isocyanides, oxazoles, thiazoles, 0301 Analytical Chemistry, 0399 Other Chemical Sciences, 0904 Chemical Engineering, General Chemistry, Organic Chemistry
    Report number: cssc.202100225
    URI: https://e-space.mmu.ac.uk/id/eprint/627300
    DOI: https://doi.org/10.1002/cssc.202100225
    ISSN 1864-5631
    e-ISSN 1864-564X

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