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Palladium and organocatalysis: An excellent recipe for asymmetric synthesis

Fernández-Ibañez, MA and Maciá, B and Alonso, DA and Pastor, IM (2013) Palladium and organocatalysis: An excellent recipe for asymmetric synthesis. Molecules, 18 (9). pp. 10108-10121. ISSN 1420-3049

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Abstract

The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology. © 2013 by the authors.

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