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    Palladium and organocatalysis: An excellent recipe for asymmetric synthesis

    Fernández-Ibañez, MA, Maciá, B, Alonso, DA and Pastor, IM (2013) Palladium and organocatalysis: An excellent recipe for asymmetric synthesis. Molecules, 18 (9). pp. 10108-10121. ISSN 1420-3049

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    Abstract

    The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology. © 2013 by the authors.

    Item Type: Article
    Peer-reviewed: Yes
    Date Deposited: 15 Mar 2019 08:42
    Publisher: MDPI
    Additional Information: This is an Open Access article published in the journal Molecules by MDPI.
    Divisions: Faculties > Science and Engineering
    Subject terms: Science & Technology, Life Sciences & Biomedicine, Physical Sciences, Biochemistry & Molecular Biology, Chemistry, Multidisciplinary, Chemistry, palladium, organocatalysis, asymmetric synthesis, dual activation, tandem reaction, allylation, fluorination, decarboxylative protonation, ENANTIOSELECTIVE DECARBOXYLATIVE PROTONATION, TRANSITION-METAL CATALYSIS, PHASE-TRANSFER CATALYST, BENZYL BETA-KETOESTERS, ALLYLIC ALKYLATION, ALPHA-FLUORINATION, ACID-CHLORIDES, ALDEHYDES, COMBINATION, AMINE, palladium, organocatalysis, asymmetric synthesis, dual activation, tandem reaction, allylation, fluorination, decarboxylative protonation, Palladium, Aldehydes, Allyl Compounds, Hydrocarbons, Fluorinated, Alkylation, Catalysis, Stereoisomerism, Models, Chemical, Halogenation, Aldehydes, Alkylation, Allyl Compounds, Catalysis, Halogenation, Hydrocarbons, Fluorinated, Models, Chemical, Palladium, Stereoisomerism, palladium, organocatalysis, asymmetric synthesis, dual activation, tandem reaction, allylation, fluorination, decarboxylative protonation, 0305 Organic Chemistry, Organic Chemistry
    URI: https://e-space.mmu.ac.uk/id/eprint/622603
    DOI: https://doi.org/10.3390/molecules180910108
    ISSN 1420-3049

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