e-space
Manchester Metropolitan University's Research Repository

    Crystal structure of (E)-4-benzylidene-6-phenyl-1,2,3,4,7,8,9,10-octahydrophenanthridine

    Al-Rubaye, BK, Brink, A, Miller, GJ, Potgieter, H and Al-Jeboori, MJ (2017) Crystal structure of (E)-4-benzylidene-6-phenyl-1,2,3,4,7,8,9,10-octahydrophenanthridine. Acta Crystallographica Section E: Crystallographic Communications, 73 (7). pp. 1092-1096. ISSN 2056-9890

    [img]
    Preview

    Available under License Creative Commons Attribution.

    Download (1MB) | Preview

    Abstract

    The preparation of the title compound, C26H25N, was achieved by the condensation of an ethano­lic mixture of benzaldehyde, cyclo­hexa­none and ammonium acetate in a 2:1:1 molar ratio. There are two crystallographically independent mol­ecules in the asymmetric unit. The two cyclo­hexyl rings adopt an anti-envelope conformation with the benzyl moiety adopting a cis conformation with respect to the nitro­gen atom of the phenanthridine segment. In the crystal, mol­ecules are linked through C—H⋯N inter­actions into hydrogen-bonded chains that are further arranged into distinct layers by weak offset π–π inter­actions.

    Impact and Reach

    Statistics

    Activity Overview
    6 month trend
    283Downloads
    6 month trend
    453Hits

    Additional statistics for this dataset are available via IRStats2.

    Altmetric

    Repository staff only

    Edit record Edit record